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Selected Publications
Dedushko, M. A.; Greiner, M. B.; Downing, A. N.; Coggins, M. K.; *Kovacs, J. A. “Electronic Structure and Reactivity of Dioxygen-Derived Aliphatic Thiolate-Ligated Fe-Peroxo and Fe(IV) Oxo Compounds.” J. Am. Chem. Soc. 2022, 144, 8515-8528

Poon, P. C. Y.; Dedushko, M. A.; Sun, X.; Yang, G.; Toledo, S.; Hayes, E. C.; Johansen, A. L.; Piquette, M. C.; Rees, J. A.; Stoll, S.; *Rybak-Akimova, E.; *Kovacs, J. A. “How Metal Ion Lewis Acidity and Steric Properties Influence the Barrier to Dioxygen Binding, Peroxo O-O Bond Cleavage, and Reactivity.” J. Am. Chem. Soc. 2019,141,15046-15057
Poon, P. C. Y.; Dedushko, M. A.; Sun, X.; Yang, G.; Toledo, S.; Hayes, E. C.; Johansen, A. L.; Piquette, M. C.; Rees, J. A.; Stoll, S.; *Rybak-Akimova, E.; *Kovacs, J. A. “How Metal Ion Lewis Acidity and Steric Properties Influence the Barrier to Dioxygen Binding, Peroxo O-O Bond Cleavage, and Reactivity.” J. Am. Chem. Soc. 2019, 141, 15046-15057
Kowalska, J. K.; Nayyar, B.; Rees, J. A.; Schiewer, C. E.; Lee, S. C.; Kovacs, J. A.; Meyer, F.; Weyermuller, T.; Otero, E.; DeBeer, S. “Iron L-edge X-ray Absorption and Magnetic Circular Dichroism Studies of Molecular Iron Complexes with Relevance to the FeMoco and FeVco Active Sites of Nitrogenase” Inorg. Chem. 2017, 56, 8147-8158.
Coggins, M. K.; Sun, X.; Kwak, Y.; *Solomon, E. I.; *Rybak-Akimova, E.; *Kovacs, J. A. “Characterization of Metastable Intermediates Formed in the Reaction Between a Mn(II) Complex and Dioxygen, Including a Crystallographic Structure of a Binuclear Mn(III)-Peroxo Species,” J. Am. Chem. Soc. 2013 135, 5631-5640.
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